I admit I'm guessing here, but my guess is that you want the output to look something like
RusselB, AWEstun, XXX, xDaeMoN
if so, then use the $addtok suggestion (which will prevent the same name from occuring more than once), and when displaying the variable, use
msg $chan $replace(%abc,$chr(44),$+($chr(44),$chr(32)))
rather than
The spaces won't actually be stored in the variable, but will be added at the proper locations when the variable is displayed in the channel (presuming that's how and where you're sending the contents of the variable)