Regular expressions are a broad issue, start out a google search for PCRE (Perl-compatible regular expressions), that's the library mIRC uses.
Here's the wiki entry , the "pcre homepage" is down atm. This page might be a point of reference, too.

In addition, there is a really helpful "introduction to regular expressions" and a "extract from pcre manual" for mIRC in the "mIRC Script Box" available at Merlin's page (online and .chm file) - unfortunately this page is down as well. Maybe one of your friends did download this comprehensive file and can share it with you. smile
I also like this tool.