There is a simple way without dragging and dropping into the mIRC directory.
If you click on that servers.ini URL I showed above you can click Open, Save or Cancel. And you can save it into the mIRC directory.
As for the server command not working, it has nothing to do with the servers.ini so that's odd why that wont work. What happens when you type: /server irc2.peacefulhaven.net
Make sure you press the return key after typing it..
It should look like..
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[04:14] * Connecting to irc2.peacefulhaven.net (6667)
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