#######START#########
on *:start:{
.server -m beastie.totalirc.net:9005
.server -m irc.freequest.net
.server -m irc.after-all.org:6000
.server -m irc.totalirc.net
.server -m irc.undermind.net
}

on *:connect:{
if ($network == freequest) {
.nick Kokarda
.msg nickserv identify password
.join #
if ($network == After-All) {
.nick Kokarda
.msg nickserv identify password
.join #
.join #
.join #
if ($network == TotalIRC) {
.nick PunkDude
.msg nickserv identify password
.join #
.join #
if ($network == UnderMind) {
.nick Kokarda
.msg nickserv identify password
.vhost
.join #
}
}
#########END#########

Ok what am I doing wrong ? And btw I have censored name of the channels and passwords. Please help me.

try instead
IF
IF
IF

use ELSEIF

Doesn't work. It says:

/if: close bracket not found (line 11, script10.mrc)

after each IF or ELSEIF you must close bracket after you open it

so copy/paste this

on *:start:{
.server -m beastie.totalirc.net:9005
.server -m irc.freequest.net
.server -m irc.after-all.org:6000
.server -m irc.totalirc.net
.server -m irc.undermind.net
}

on *:connect:{
if ($network == freequest) {
.nick Kokarda
.msg nickserv identify password
.join #
}
elseif ($network == After-All) {
.nick Kokarda
.msg nickserv identify password
.join #
.join #
.join #
}
elseif ($network == TotalIRC) {
.nick PunkDude
.msg nickserv identify password
.join #
.join #
}
elseif ($network == UnderMind) {
.nick Kokarda
.msg nickserv identify password
.vhost
.join #
}
}

Just to add.... on the 2nd line you should have /server and not /server -m. This way you won't have an extra status window open with nothing it relates to.

Thanks so much for help. Everything works perfect.