! is also used for Admin. & is also referred to as a Protected Op and if you happen to have all of those modes, the order would be:
~, !, &, @, %, +, N/A
And, as RusselB mentioned, this is specific to each network (some only have @ and +). And what the different modes let you do on a given network can vary, so it's best to check with that network's #help channel for details (or just try it out).